My top Five:
1 - Frollo
2 - Scar
3 - Mother Gothel (I know she's newer but I love)
4 - Malificent
5 - tie between Hades and Ursula
I can't even decide! I loved (excuse me, still love) Scar. I think the other villain I love most would have to be Captain Hook, like Jessemyn below me
I really need to watch some disney movies now...
In no particular order:
Scar: how can you miss him, just a beast!
Ursula: Very quite feisty and dripping with evilness
The Horned King: The Black Cauldron is the darkest disney movie, and the Horned King never fails to freak me out
Captain Hook: Such a cowardly bastard but brings a sort of class to the villain side
Madame Medusa: Sly, arrogant, demanding, has excellent sidekicks, what more can u ask for?
3. Forte (from Beauty and the Beast: The Enchanted Christmas)
5. Shere Khan
And if you allowed a 6th villain, Cruella De Vil is high up on my list too. :)
3) Judge Frollo
3. Scar/ Dr. Facilier
5. Oogie Boogie